Palladium-catalysed allylic alkylation of allylic nitro compounds with stabilized carbanions
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1439-1443
- https://doi.org/10.1039/p19860001439
Abstract
In the presence of a catalytic amount of Pd(PPh3)4, allylic nitro compounds (1) undergo allylic alkylation with stabilized carbanions to give a mixture of two regio-isomers (2) and (3). The product ratio (2) : (3) is controlled both by the nature of the substituents of π-allyl unit and the steric factors of the nucleophiles and ligands.Keywords
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