Band dispersion in(111): An angle-resolved photoemission study
- 15 October 1994
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 50 (15) , 11239-11242
- https://doi.org/10.1103/physrevb.50.11239
Abstract
Angle-resolved photoemission studies of single-crystal (111) films grown on GeS(001) reveal changes in valence feature line shape with emission angle and photon energy that are indicative of band dispersion. For an excitation energy (hν) of 10 eV, normal emission spectra show four sharp structures within the ∼1.1-eV-wide valence feature derived from the second highest molecular orbital (HOMO-1) of . For hν=8.1 eV, the 1-eV-wide HOMO-derived feature exhibits changes with emission angle mainly due to dispersion of 0.6 eV in the unoccupied bands. The distribution of electronic states underlying HOMO and HOMO-1 indicates that vibronic loss structures are not necessary to explain the width of these valence features.
Keywords
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