Selective Synthesis of a Functionalised Enantiopure Cyclopentane Derivative for the Preparation of Steroids

1 January 1993

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1993 (04) , 291-292
https://doi.org/10.1055/s-1993-22436

Abstract

The enantiopure cyclopentane-carbaldehyde 4 was synthesised from the keto ether 6 by a palladium catalyzed hydrogenolysis of the allylic formate 10 followed by a regioselective ozonolysis.

Keywords

FUNCTIONALISED
CYCLOPENTANE
ENANTIOPURE
CARBALDEHYDE
PALLADIUM
OZONOLYSIS
STEROIDS
ALLYLIC
REGIOSELECTIVE
ETHER

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