Synthesis, photophysics and electrochemistry of [Au2(dppf)R2][dppf = Fe(η-C5H4PPh2)2; R = alkyl, aryl or alkynyl]. Crystal structure of [Au2(dppf)(C16H9)2](C16H9= pyren-1-yl)
- 1 January 1996
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 16,p. 3411-3415
- https://doi.org/10.1039/dt9960003411
Abstract
A series of organometallic complexes [Au2(dppf)R2][dppf = Fe(η-C5H4PPh2)2; R = Me, Ph, 1-naphthyl, 9-anthryl, pyren-1-yl (C16H9), CCPh or CCBut] have been synthesized. Their photophysical and electrochemical properties have been studied. Both excimer and exciplex formation are evidenced in [Au(dppf)2(C16H9)2]. The crystal structure of the latter has been determined.Keywords
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