Selective Gas Sorption within a Dynamic Metal-Organic Framework
- 20 September 2007
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 46 (21) , 8705-8709
- https://doi.org/10.1021/ic7013573
Abstract
A microporous metal-organic framework 1 Co(NDC)(4,4‘-Bipy)0.5·Gx (NDC = 2,6-naphthalenedicarboxylate; 4,4‘-Bipy = 4,4‘-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200 °C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.Keywords
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