Homogeneous catalytic activation of Grignard reagents by nickel complexes. A new stereospecific method for reduction of alkoxy-, chloro-, and fluoro-silanes
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 164-165
- https://doi.org/10.1039/c39730000164
Abstract
A highly stereospecific preparative route to R1R2R3Si*H is described involving the reaction between R1R2R3Si*X (X = OMe, F, or Cl) and Grignard reagents possessing β-hydrogens (Et, Prn, Pri, Bun, Bui) activated by a nickel catalyst.Keywords
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