Spectroelectrochemical Characterization of the Two-Step Redox System {(μ-pz)[Os(CN)5]2}n-(n= 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz−Taube System
- 1 January 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 37 (2) , 311-316
- https://doi.org/10.1021/ic970804o
Abstract
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This publication has 68 references indexed in Scilit:
- The mpz+/mpz•Pair as Organic Analogue of the NO+/NO•Ligand Redox System (mpz =N-Methylpyrazinium). A Combined Electrochemical and Spectroscopic Study (UV/Vis/NIR, IR, EPR) of Complexes [(mpz)M(CN)5]2-/3-(M = Fe, Ru, Os)Inorganic Chemistry, 1997
- Tetranuclear Pentaammineruthenium Complexes Bridged by .pi.-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation StatesInorganic Chemistry, 1995
- Chemical and Electrochemical Generation of Hydride-Forming Catalytic Intermediates (bpy)M(CnRn): M = Rh, Ir (n = 5); M = Ru, Os (n = 6). Coordinatively Unsaturated Ground State Models of MLCT Excited States?Inorganic Chemistry, 1994
- Mixed-valent interactions in rigid dinuclear systems: electrochemical and spectroscopic studies of CrICr0 ions with controlled torsion of the biphenyl bridgeInorganic Chemistry, 1994
- Stability rules for d5/d6 mixed-valent dimers. Effects from the donor/acceptor capability of the metal (ruthenium vs osmium) and from the occupancy of the mediating ligand orbital (LUMO vs HOMO)Inorganic Chemistry, 1990
- Pyrazine-bridged complexes. Synthesis of and spectroscopic studies on binuclear pyrazine complexes of osmium, ruthenium and rhodium amminesInorganic Chemistry, 1988
- Solvent dependences of spectral and redox properties of pyrazine (pz) complexes of ruthenium and osmium pentaammines: Ru(NH3)5pzCH33+, OS(NH3)5pzCH33+, and [Ru(NH3)5]2pz5+Inorganic Chemistry, 1987
- The Creutz-Taube complex revisited: a single-crystal EPR studyInorganic Chemistry, 1984
- Die vielseitige Chemie der 1,4-Diazine: Organische, anorganische und biochemische AspekteAngewandte Chemie, 1983
- Intervalence transfer and electron transfer in the mixed-valence ion dichlorotetrakis(bipyridine)pyrazinediruthenium(3+)Journal of the American Chemical Society, 1977