Generation and Carbonyl Addition of Dibromofluoromethyllithium
- 1 September 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (09) , 987-988
- https://doi.org/10.1055/s-1995-5145
Abstract
When CFBr3 was treated with n-BuLi at -130 °C, thermally labile LiCFBr2 was generated which reacted smoothly with a coexisting electrophile RR’CO to give an adduct RR’C(OH)CFBr2 in good yield.Keywords
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