Molecular Models of Surface Relaxation, Hydroxylation, and Surface Charging at Oxide-Water Interfaces
- 1 January 2001
- journal article
- Published by Mineralogical Society of America in Reviews in Mineralogy and Geochemistry
- Vol. 42 (1) , 169-198
- https://doi.org/10.2138/rmg.2001.42.6
Abstract
Increasingly sophisticated experimental techniques are resolving detailed aspects of the surface chemistry of oxide and silicate materials. Structural characterization can now be carried out on remarkably complex systems (Brown et al. 1999). Recent examples include the distribution of iron in dioctahedral smectites (Manceau et al. 2000), the arrangements of protons on the hematite (012) surface (Henderson et al. 1998), the relaxation of iron atoms at the surface of hematite (001) (Thevuthasan et al. 1999), the arrangements of defects in the γ-Fe2O3 corrosion film formed on metallic iron (Ryan...Keywords
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