Intramolecular competition experiments on sulphide vs. thiocarbonyl oxidation. Evidence for electronic and steric deactivation of thiocarbonyl groups
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 797-798
- https://doi.org/10.1039/c39830000797
Abstract
Addition of m-chloroperbenzoic acid (6) to the thiane-derived thioketene (1) or the thioketone (8) leads to selective oxidation of their respective sulphide groups.Keywords
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