Chiral diamines. Part 3: Effect of ligand structure on the enantioselective deprotonation of N-Boc-pyrrolidine with i-PrLi: a computational comparison of (−)-sparteine and (S,S)-1,2-bis(N,N-dimethylamino)cyclohexane
- 2 December 2000
- journal article
- research article
- Published by Elsevier in Tetrahedron Letters
- Vol. 41 (49) , 9365-9368
- https://doi.org/10.1016/s0040-4039(00)01353-8
Abstract
No abstract availableThis publication has 12 references indexed in Scilit:
- (−)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted 5-Hexynyl Carbamates. Synthesis of Enantiopure 1,3-Difunctionalized Alkylidene CyclopentanesThe Journal of Organic Chemistry, 1999
- Enantioselektive Synthese mit Lithium/(−)‐Spartein‐Carbanion‐PaarenAngewandte Chemie, 1997
- Regioselective, Diastereoselective, and Enantioselective Lithiation−Substitution Sequences: Reaction Pathways and Synthetic ApplicationsAccounts of Chemical Research, 1996
- Chiral Organolithium Complexes: The Effect of Ligand Structure on the Enantioselective Deprotonation of Boc-PyrrolidineThe Journal of Organic Chemistry, 1995
- Complex Induced Proximity Effects: Enantioselective Syntheses Based on Asymmetric Deprotonations of N-Boc-pyrrolidinesJournal of the American Chemical Society, 1994
- Stereoselective Generation of 1‐Acyloxy‐2‐amino Carbanions by Deprotonation; Synthesis of Enantiomerically and Diastereomerically Pure β‐Amino AlcoholsAngewandte Chemie International Edition in English, 1992
- Enantioselective deprotonation: the structure and reactivity of an unsymmetrically complexed isopropyllithium/sparteine/Et2O dimerJournal of the American Chemical Society, 1992
- Asymmetric deprotonations: enantioselective syntheses of 2-substituted tert-(butoxycarbonyl)pyrrolidinesJournal of the American Chemical Society, 1991
- Chiral Lithium‐1‐oxyalkanides by Asymmetric Deprotonation; Enantioselective Synthesis of 2‐Hydroxyalkanoic Acids and Secondary AlkanolsAngewandte Chemie International Edition in English, 1990
- C2 symmetry and asymmetric inductionChemical Reviews, 1989