Synthesis of Scroll‐Type Composite Microtubes of Mo2C/MoCO by Controlled Pyrolysis of Mo(CO)6
- 15 January 2004
- journal article
- Published by Wiley in Chemistry – A European Journal
- Vol. 10 (2) , 433-439
- https://doi.org/10.1002/chem.200305213
Abstract
Composite microtubes of Mo2C/MoCO have been synthesized for the first time under well‐controlled conditions by thermal decomposition of Mo(CO)6 at about 600 °C. Here, thermal stability and phase transition of the products, as well as the influence of reaction temperature and argon flow rate, have been carefully investigated. All samples were characterized by X‐ray powder diffraction (XRD), scanning electron microscopy (SEM), and X‐ray photoelectron spectroscopy (XPS). The reaction model and rolling mechanism were proposed on the basis of the experimental facts.Keywords
This publication has 54 references indexed in Scilit:
- Rare Earth Compound NanotubesAdvanced Materials, 2003
- Nanotubes of Group 4 Metal DisulfidesAngewandte Chemie International Edition in English, 2002
- Oxidic Nanotubes and Nanorods—Anisotropic Modules for a Future NanotechnologyAngewandte Chemie International Edition in English, 2002
- Nanoröhren und Nanostäbe auf Oxidbasis – anisotrope Bausteine für künftige NanotechnologienAngewandte Chemie, 2002
- From Surfactant–Inorganic Mesostructures to Tungsten Nanowires The authors thank Prof. G. D. Stucky for helpful discussions. This work was supported by the National Science Foundation of China and the State key project of Fundamental Research for Nano-materials and Nano-structures.Angewandte Chemie International Edition in English, 2002
- From Surfactant-Inorganic Mesostructures to Tungsten NanowiresAngewandte Chemie, 2002
- Redox-Active Nanotubes of Vanadium OxideAngewandte Chemie International Edition in English, 1998
- Redoxaktive Nanoröhren aus VanadiumoxidAngewandte Chemie, 1998
- Processing and properties of (Mo,Cr) oxycarbides from MOCVDApplied Organometallic Chemistry, 1998
- New Crystal Structures of WS2: Microtubes, Ribbons, and RopesAdvanced Materials, 1998