Biosynthetic short activation of the 2,3,6-trideoxysugar l-rhodinose
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 973-974
- https://doi.org/10.1039/a702125i
Abstract
The successful incorporation of non-activated [2,3- 2 H 2 ]-L-rhodinose 4b into landomycin A 7 proves the existence of a short activation pathway for L-rhodinose 4; this result provides evidence of a general saving pathway for deoxy-sugar building blocks and their biosynthetic intermediates, respectively, which become accidentally deactivated during the biosynthetic deoxygenation cascades.Keywords
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