Manipulation of the nuclear overhauser effect by the use of a viscous solvent: the solution conformation of the antibiotic echinomycin
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 165-166
- https://doi.org/10.1039/c39810000165
Abstract
In an experiment which should be of wide applicability, a viscous solvent has been used to induce relatively slow tumbling of the solute; under these conditions, negative n.O.e.'s may be observed and, in the present case, these have been used to deduce the solution conformation of echinomycin.Keywords
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