Anisotropic Spin‐Orbit Coupling Contribution to the Zero‐Field Splitting of 3d⁵ Ions

1 July 1973

journal article
research article
Published by Wiley in Physica Status Solidi (b)

Vol. 58 (1) , 293-299
https://doi.org/10.1002/pssb.2220580128

Abstract

The crystal field potential contributes directly to the spin‐orbit interaction. Effective Hamiltonians describing this interaction are used to calculate the magnitude of this effect in the ground state splitting of 3d⁵ ions. Numerical results are given for ZnF₂:Mn²⁺.

Keywords

This publication has 6 references indexed in Scilit:

Spin-Orbit Coupling in Ions in Crystals
Physica Status Solidi (b), 1972
Zero-Field Splitting of $S$ -State Ions. III. Corrections to Parts I and II and Application to Distorted Cubic Crystals
Physical Review B, 1968
Zero-Field Splitting of $S$ -State Ions. II. Overlap and Covalency Model
Physical Review B, 1967
Zero-Field Splitting of $S$ -State Ions. I. Point-Multipole Model
Physical Review B, 1966
Spin-Lattice Relaxation of $S$ -State Ions: ${Mn}^{2 +}$ in a Cubic Environment
Physical Review B, 1962
Iron Series Hartree-Fock Calculations
Physical Review B, 1960

Anisotropic Spin‐Orbit Coupling Contribution to the Zero‐Field Splitting of 3d5 Ions

Abstract

Keywords

Anisotropic Spin‐Orbit Coupling Contribution to the Zero‐Field Splitting of 3d⁵ Ions