Combination of ring-opening polymerization and “click” chemistry towards functionalization of aliphatic polyesters
- 26 September 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 42,p. 5334-5336
- https://doi.org/10.1039/b510282k
Abstract
Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 °C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.Keywords
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