Thermodynamics of formation of 18-crown-6 complexes with arenediazonium and anilinium salts in methanol at 25 °C
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 386-387
- https://doi.org/10.1039/c39780000386
Abstract
Binding of 18-crown-6 to arenediazonium cations, which has previously been shown to stabilize the cation against decomposition, is found to be very sensitive to electronic factors and much more sensitive to steric factors than is binding to corresponding anilinium cations.Keywords
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