Ein neues Cobaltphosphat mit Hohlraumstruktur und tetraedrisch koordinierten CoII‐Zentren: CoPO4 · 0.5 C2H10N2
- 17 March 1994
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 106 (6) , 667-668
- https://doi.org/10.1002/ange.19941060608
Abstract
Ein Netzwerk aus alternierenden, eckenverknüpften Co4,‐ und PO,4‐Tetraedern bildet die blaue Titelverbindung, deren CoII‐Zentren ausschließlich – wie die Farbe andeutet – tetraedrisch umgeben sind. Die Kanäle, deren Porenöffnungen in einer Richtung aus regelmäßigen. sonst gestauchten Achtecken gebildet werden, sind parallel zu den kristallographischen Achsen angeordnet.Keywords
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