Synthesis and characterization of the dimeric [Mn(salen)(CO)]2(ClO4)2[salen =N,N′-ethylenebis(salicylideneaminato)], a carbonyl complex of a metal in the +3 oxidation state
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 436-437
- https://doi.org/10.1039/c39830000436
Abstract
The synthesis and characterization of [Mn(salen)(CO)]2(ClO4)2[salen N,N′-ethylenebis(salicylideneaminato)], the first carbonyl complex of a first row transition metal in the +3 oxidation state, are reported; the formation of such a complex is critically dependent on the nature of the polymethylene chain in the Schiff's base ligand.Keywords
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