Kinetics of the oxidation of some meta- and para-substituted dimethylanilines with lead tetra-acetate
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 15,p. 1803-1805
- https://doi.org/10.1039/p29760001803
Abstract
The second-order kinetics of the oxidation of some aryldimethylamines with lead tetra-acetate in chloroform-acetic anhydride (1 :1 v/v) to give acetamides and formaldehyde follow the equation –d[LTA]/dt=k[LTA][amine]. The obtained ρ value (–2.4 ± 0.5) is consistent with the presence of a positive charge in the transition state.Keywords
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