The effect of N-methylation on the chemical reactivity of binuclear Ni amine-thiophenolate complexes
- 6 July 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1376-1377
- https://doi.org/10.1039/b103050g
Abstract
Macrocyclic amine thiophenolate ligands are shown to form face-sharing bioctahedral nickel complexes with a central N3Ni(μ-SR)2(μ-Cl)NiN3 core structure. The bridging halide ion can be readily replaced when all six nitrogen atoms are tertiary amine donors.Keywords
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