Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]: a new type of magnesiate complex free of a donor solvent as ligand
- 1 January 1993
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 969-970
- https://doi.org/10.1039/c39930000969
Abstract
A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (BunLi), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N–Li coordinations in the solid state.Keywords
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