The Trivalency of Gallium Ions Formed during the Dissolution of the Metal in Acids
Open Access
- 1 January 1964
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 111 (7) , 795-853
- https://doi.org/10.1149/1.2426255
Abstract
Theoretical calculations of the electrolytic separation factors for the slow discharge mechanism were carried out following the lines of earlier calculations by Horiuti et al. Previous calculations neglected the effect on of (i) the step following the discharge step, (ii) the real stretching frequency of the transition state, and (iii) tunneling corrections. The presently calculated values differ from previous results mainly due to the inclusion of the real stretching frequency of the transition state. The H‐T separation factors are more useful than the H‐D separation factors in determining the mechanism.Keywords
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