Ring-disc electrodes. Part 7.—Homogeneous and heterogeneous kinetics
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 62, 2596-2606
- https://doi.org/10.1039/tf9666202596
Abstract
In this paper we calculate the value of N for the system where the intermediate formed on the disc electrode is reversibly but almost wholly converted into a second intermediate in a homogeneous reaction; this second intermediate returning through the first intermediate is destroyed at the ring electrode. We also calculate the effect of homogeneous kinetics and of slow electrochemical kinetics at a simple ring electrode and the effect of slow electrochemical kinetics for the ring-disc electrode. The results are discussed and a table summarizing the chemical and electrochemical systems dealt with in this series of papers is given.Keywords
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