Phase transitions in a model porous medium
- 1 August 1993
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 48 (5) , 3124-3129
- https://doi.org/10.1103/physrevb.48.3124
Abstract
An exact solution is presented for Ising-like transitions in a decorated lattice model of a porous medium. The model is solved by decimation of the spins, leading to a space-filling lattice with renormalized parameters. The critical temperature is found to vary as 1/lnL, where L is the number of sites between intersections of the spin chains. Some of the critical exponents differ from those of the ordinary Ising problem. We have also studied the case of a single, infinitely long pore, using both exact and approximate methods. An exploration of finite-width effects reveals surprisingly small (quantitative) deviations from mean-field theory.Keywords
This publication has 19 references indexed in Scilit:
- Ordering and phase transitions in random-field Ising systemsPhysical Review Letters, 1991
- Effect of dilute silica gel on phase separation of a binary mixturePhysical Review Letters, 1991
- Liquid-vapor critical point ofin aerogelPhysical Review Letters, 1990
- Superfluid critical behavior inporous mediaPhysical Review Letters, 1990
- Temperature dependence of gas adsorption on a mesoporous solid: capillary criticality and hysteresisLangmuir, 1989
- Wetting and Random-Field Transition of Binary Liquids in a Porous MediumPhysical Review Letters, 1989
- Disorder and the Superfluid Transition in LiquidPhysical Review Letters, 1988
- Superfluid Films in Porous MediaPhysical Review Letters, 1988
- Random-field transition of a binary liquid in a porous mediumPhysical Review Letters, 1987
- Liquid-liquid demixing inside a rigid network. Qualitative featuresThe Journal of Physical Chemistry, 1984