Iridium(I), -(III), and -(V) complexes of an O-donor ligand in alkyne hydrosilylation

Abstract
The O-donor ligand C(Ph2PO)3 (triso) stabilises iridium-(I), -(III), and -(V) species such as [(triso)IrH2(SiMePh2)2]; the complexes catalyse the net anti-addition of silanes to alkynes.

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