Efficient Syntheses of Amadori Rearrangement Compounds

Abstract
Various types of 1-amino-1-deoxy-2-ketoses, Amadori rearrangement compounds, have bee synthesized using a reduction amination of the 1-formyl derivative (3), prepared from 2,3:4,5-di-O-isopropylidene-D-fructopyranose (2), with unprotected or partially protected amino acids in a few steps.

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