Versatile behaviour of the phosphanyl salt (Pri 2N)2 P+CF3SO3 ? towards zirconocene derivatives
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1487-1489
- https://doi.org/10.1039/c39930001487
Abstract
Transfer reactions of various groups (Ph2P[CH2]3–, Ph2CCPh–CHN–, N3, CN, Me, Cl, H) occurred from zirconium to phosphorus in reactions of the phosphanylium salt (Pri 2N)2 P+CF3SO3 – with zirconocene derivatives; the crystal structure of (Pri 2N)2P–CHN–P(NPri 2)28 has been determined.Keywords
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