Infinitely thin disks exhibit a first order nematic-columnar phase transition
- 1 April 1998
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 57 (4) , 4824-4826
- https://doi.org/10.1103/physreve.57.4824
Abstract
We have investigated the phase behavior of a system of hard cylinders in the limit . Simulations in this limit are possible because the model can be mapped onto a system of particles with finite volume but variable shape. Our simulations indicate that infinitely thin disks exhibit a columnar phase, and that the nematic-columnar transition is first order. Combining this result with previous simulations of cut spheres, this transition appears to be first order for all aspect ratios .
Keywords
This publication has 9 references indexed in Scilit:
- First-order nematic-smectic phase transition for hard spherocylinders in the limit of infinite aspect ratioPhysical Review E, 1997
- Tracing the phase boundaries of hard spherocylindersThe Journal of Chemical Physics, 1997
- A re-examination of the phase diagram of hard spherocylindersThe Journal of Chemical Physics, 1996
- Phase behavior of disklike hard-core mesogensPhysical Review A, 1992
- The hard ellipsoid-of-revolution fluidMolecular Physics, 1985
- Monte Carlo study of the isotropic and nematic phases of infinitely thin hard plateletsMolecular Physics, 1984
- Liquid crystals of disc-like moleculesPhilosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1983
- Liquid crystals of disc-like moleculesPramana, 1977
- Die Erforschung der molekularen Gestalt mit Hilfe der kristallinischen FlüssigkeitenZeitschrift für Physikalische Chemie, 1923