Formation de l'acide pipécolique chez Triglochin maritima

Abstract
Radioactive D-lysine supplied to Triglochin maritima L. shoots can be utilized without configuration inversion. The pipecolic acid is the most radioactive compound. It would be synthetized via the α-ceto-ε-aminocaproïc acid.In the plant, L-lysine can be partly converted into D-lysine; however, the data obtained in the presence of L-[3H1-lysine suggest the possibility of a direct transformation of the L-isomer into pipecolic acid via the adipic semialdehyde.In all cases, the labelled pipecolic acid is the L-enantiomer that is more radioactive in presence of sodium chloride.

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