Structural studies on lipiarmycin I. Characterization by 1H and 13C NMR spectroscopy and isolation of methyl 2-O-methyl-4-O-homodichloroorsellinate-.BETA.-rhamnoside.

Abstract
1H and 13C NMR spectral studies of lipiarmycin in 3H-labeled CHCl3 and pyridine-d5 provided evidence for the 6 partial structures and the 2 sugar units. Acid methanolysis led to the isolation of methyl 2-O-methyl-4-O-homodichloroorsellinate-.beta.-rhamnoside, whose structure was determined by spectroscopic methods.

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