Substituent Effects of Ligands on Asymmetric Induction in a Prototypical Palladium-Catalyzed Allylation Reaction: Making Both Enantiomers of a Product in High Optical Purity Using the Same Source of Chirality
- 16 September 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 64 (20) , 7601-7611
- https://doi.org/10.1021/jo9911387
Abstract
No abstract availableKeywords
This publication has 57 references indexed in Scilit:
- Palladium‐Catalyzed Allylic Alkylation with Phosphinoaryldihydrooxazole Ligands: First Evidence and NMR Spectroscopic Structure Determination of a Primary Olefin–Pd0 ComplexAngewandte Chemie International Edition in English, 1997
- Molecular Mechanics Predictions and Experimental Testing of Asymmetric Palladium-Catalyzed Allylation Reactions Using New Chiral Phenanthroline LigandsJournal of the American Chemical Society, 1996
- Palladium-Catalyzed Asymmetric Allylic Amination Using Ferrocenyl Pyrazole Ligands: Steric Control of η3-Allyl Configuration and Site-Selective Nucleophilic AttackJournal of the American Chemical Society, 1996
- Palladium .pi.-Allyl Chemistry of New P,S Bidentate Ligands. Selective but Variable Dynamics in the Isomerization of the .eta.3-C3H5 and .eta.3-PhCHCHCHPh .pi.-Allyl LigandsOrganometallics, 1995
- An Unusual, Selective .eta.3-.eta.1 Allyl Isomerization in a Chiral Allylic Alkylation CatalystJournal of the American Chemical Society, 1994
- Chiral semicorrins and related nitrogen heterocycles as ligands in asymmetric catalysisAccounts of Chemical Research, 1993
- Molecular mechanics and NOE investigations of the solution structures of intermediates in the [rhodium(chiral bisphosphine)]+-catalyzed hydrogenation of prochiral enamidesJournal of the American Chemical Society, 1993
- Tailored ligands for asymmetric catalysis: the hydrocyanation of vinyl arenesJournal of the American Chemical Society, 1992
- Design Concepts for Developing Highly Efficient Chiral Bisphosphine Ligands in Rhodium-Catalyzed Asymmetric HydrogenationsSynlett, 1992
- A model for metal-templated catalytic asymmetric induction via .pi.-allyl fragmentsOrganometallics, 1985