CO2 fixation and activation by metal complexes of small polyazacyclophanes
- 28 June 2001
- journal article
- research article
- Published by Wiley in Journal of Physical Organic Chemistry
- Vol. 14 (7) , 495-500
- https://doi.org/10.1002/poc.400
Abstract
The interaction of the cyclophanes 2,6,9,13‐tetraaza[14]paracyclophane (L1) and 2,6,9,13‐tetraaza[14]metacyclophane (L2) and of their Zn2+ and Cu2+ complexes with CO32− and its protonated forms is described. The actuation of the Cu2+–L2 system as an electrocatalyst for the reduction of CO2 to CO in water is advanced. Copyright © 2001 John Wiley & Sons, Ltd.Keywords
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