Single-crystal study of Prussian Blue: Fe4[Fe(CN)6]2, 14H2O
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1299
- https://doi.org/10.1039/c39720001299
Abstract
A single-crystal X-ray structure analysis of Prussian Blue, Fe4[Fe(CN)6]3,14H2O, reveals that the space group symmetry of the approximate structure is Oh 5-Fm3m with occupancy factors of 0·75 for FeII, C, and N; the more detailed investigation demonstrates deviations from the cubic face-centred symmetry.Keywords
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