Electron spin resonance spectra of ester radical cations; evidence for hydrogen atom migration
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 4,p. 625-628
- https://doi.org/10.1039/p29860000625
Abstract
Exposure of CH3CO2CHD2 in dilute solutions in CFCI3 to 60CO γ-rays at 77 K or to X-rays at ca. 4 K gave only the rearranged cation CH3C(OH+)–OĊD2, as detected by e.s.r. spectroscopy. This result is discussed in the light of current ideas concerning the structures of ester radical cations.Keywords
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