Fine structure effect on the charge transfer reaction of Ar+(2P3/2,1/2)+N2 (X̃ 1Σ+g, v=0)
- 1 February 1986
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 84 (3) , 1948-1950
- https://doi.org/10.1063/1.450399
Abstract
The relative spin‐orbit‐state‐selected total charge transfer cross sections, σ3/2 and σ1/2, for the reactions, Ar+ (2P3/2,1/2)+N2 (X̃ 1∑+g ,v=0) → Ar+N+2 at the center‐of‐mass collision energy (Ec.m.) range of 0.41–164.7 eV, have been determined using the photoionization and crossed ion–neutral beam methods. The kinetic energy dependences for σ1/2/σ3/2 is found to exhibit a minimum at Ec.m.≊3.3 eV, an observation consistent with the prediction of a recent semiclassical theoretical calculation of Spalburg and Gislason.Keywords
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