Aziridination of vinylsilanes and vinylstannanes: a new synthesis of azirines

Abstract
Aziridination of vinylsilanes and vinylstannanes with the N-acetoxyaminoquinazolone (8) gave aziridines (1)–(7): caesium fluoride in dimethylformamide brought about elimination of trimethylsilyl and quinazolone groups from (1) and (2) to give the corresponding azirines.

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