Protonation of decamethylsilicocene [bis(pentamethylcyclopentadienyl)silicon]
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 305-306
- https://doi.org/10.1039/c39880000305
Abstract
In general, decamethylsilicocene (1) reacts with Brønsted acids under oxidative addition yielding SiIV compounds of the type (Me5C5)2Si(H)X (2)–(7); as an exception, the cyclotetrasilane (Me5C5SiF)4(8) is formed in the reaction with tetrafluoroboric acid and has been characterized by an X-ray diffraction study.Keywords
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