Reactions of the 1-adamantyl-vinyl cation in sulphuric acid
- 1 January 1970
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 10,p. 599-600
- https://doi.org/10.1039/c29700000599
Abstract
The adamantyl cation with acetylene in sulphuric acid is shown to give an intermediate sulphate which is the precursor of 1-adamantylacetaldehyde or of 1-methylhomoadamantan-2-one, depending on the amount of water present: with carbon monoxide a retrogression is observed giving adamantane-1-carboxylic acid, and in the presence of bromide the acetylene reaction leads to adamantyl methyl ketone.Keywords
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