Metal hydrides from cationic rhodium(I) catalyst precursors. X-Ray structure of [(L–L)HRh(µ-H)3RhH(L–L)]ClO4[L–L =rac-Fe(η5-C5H4PPhBut)2]
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 719-721
- https://doi.org/10.1039/c39840000719
Abstract
The hydrogenation catalyst precursor [(L–L)RhNBD]ClO4 reacts with H2(1 atm, 30 °C, MeOH) to yield [(L–L)HRh(µ-H)3RhH(L–L)]ClO4[L–L =rac-Fe(η5-C5H4PPhBut)2; NBD = norbornadiene].Keywords
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