Elastic behavior under pressure of the vacancy compounds Hg5Ga2Te8, Hg3In2Te6, and HgIn2Te4

Abstract
Hg5 Ga2Te8, Hg3 In2Te6, and HgIn2Te4 are semiconducting vacancy compounds which may be thought of as having tetrahedrally coordinated structures with a sublattice of unfilled sites. Measurements of the hydrostatic pressure dependences of ultrasonic-wave transit times in single crystals of these compounds have been made and used to obtain the pressure derivatives of the elastic-stiffness constants. The elastic behavior of these compounds under pressure is compared with that of the "parent" zinc-blende-structure compound HgTe. It is found that the compression V(P)V0 of the vacancy compounds becomes larger as the proportion of empty cation sites is increased. The effect of hydrostatic pressure on the gradient of the acoustic-phonon branches at the Brillouin-zone center is discussed in terms of the mode-Grüneisen gammas. The presence of the sited vacancies is shown to inhibit the softening of shear modes characteristic of HgTe and related zinc-blende-structure compounds. Thus, for vacancy compounds, the shear-to-bulk modulus ratios 12(C11C12)B and C44B, or the ratio βα of the bond-bending to -stretching force constants, do not reach the limiting values for crystal stability and the densification transition until much higher pressures than that found for HgTe.

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