A New Synthetic Approach to Substituted Group VI Metal Carbonyl Anions; M(CO)5X[sbnd]
- 1 January 1971
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 1 (3) , 215-219
- https://doi.org/10.1080/00945717108057573
Abstract
A simple, rapid synthesis of Group VI metal carbonyl anions of the type M(CO)5X[sbnd], (X = CN, SCN, l, Cl, and C [tbnd] CC6H5) has been found. Reaction of the dinuclear anions, M2(CO)10 [dbnd], with either silver salts, AgX, or mercuric salts, HgX2, affords the corresponding mononuclear anions in moderate to good yieldsKeywords
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