FORMATION OF α-TRICHLOROSTANNYL KETONES IN THE REACTION OF STANNIC CHLORIDE WITH ENOL SILYL ETHERS
- 5 January 1983
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 12 (1) , 59-62
- https://doi.org/10.1246/cl.1983.59
Abstract
The enol silyl ethers of ketones reacted with SnCl4 to give α-trichlorostannyl ketones in moderate to good yields, and their structures were determined by chemical and spectral means. The reaction mechanism is also discussed.Keywords
This publication has 6 references indexed in Scilit:
- The metal effect on aldol type stereoselection. Erythro-selective condensations with aldehydes via .alpha.-mercurio ketonesJournal of the American Chemical Society, 1982
- Regiochemical aspects in the reaction of 2,3,5-tri-o-benzoyl-d-ribofuranosylTetrahedron Letters, 1982
- Stereo- and regio-controlled aldol synthesisTetrahedron Letters, 1980
- Chemistry of carbanions. XXII. C- vs. O-acylation of metal enolatesThe Journal of Organic Chemistry, 1973
- Generation, nuclear magnetic resonance spectra, and alkylation of enolates from trialkylsilyl enol ethersJournal of the American Chemical Society, 1968
- Table of Conformational Energies—1967Topics in Stereochemistry, 1967