Evidence for reversible α-hydrogen abstraction from methyl-cobalt and -rhodium complexes involving the possible formation of hydrido-carbene intermediates
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 9-10
- https://doi.org/10.1039/c39740000009
Abstract
Evidence for a reversible α-hydrogen abstraction from methyl groups of CoCH3(PPh3)3 and RhCH3(PPh3)3 involving intermediate carbene-hydride formation is presented on the basis of the mass spectrometric analysis of polydeuteriated methanes formed in the reaction of D2 with CoCH3(PPh3)3 and RhCH3(PPh3) in toluene.Keywords
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