Stereochemistry of a Michaelis–Arbusov reaction: alkylation of optically active ethyl trimethylsilyl phenylphosphonite with retention of configuration
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 12,p. 606-607
- https://doi.org/10.1039/c29710000606
Abstract
Ethylation of ethyl phenylphosphinate (I)via ethyl trimethylsilyl phenylphosphonite or via the corresponding trimethylstannyl ester, and free-radical addition of (I) to ethylene proceed with complete, or almost complete, retention of configuration.Keywords
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