A green protocol for the silylation of alcohols using bonded fluorous phase catalysisThis work was presented at the Green Solvents for Catalysis Meeting, held in Bruchsal, Germany, 13–16th October 2002.

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Abstract
The surface of a solid silica support has been functionalized with long perfluoroalkyl chains. The resulting surface layer readily adsorbs fluorous molecules from organic solutions. In this way, dirhodium(II) perfluorocarboxylate catalysts can be conveniently immobilized on a solid support. The resulting Bonded Fluorous Phase (BFP) catalysts display a high activity in the silane alcoholysis reaction using a solventless procedure and are easily recycled.

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