Recursive formulas for Morse-oscillator matrix elements of arbitrary powers of 1−exp[−a(r−r e)]
- 1 February 1983
- journal article
- Published by AIP Publishing in Journal of Mathematical Physics
- Vol. 24 (2) , 397-398
- https://doi.org/10.1063/1.525693
Abstract
The variable y=1−exp[−a(r−re)] is a natural one to use in connection with a Morse oscillator. A simple formula is derived via the factorization method relating the Morse matrix element 〈0‖ yn ‖0〉 to 〈0‖yn−1 ‖0〉 and 〈0‖yn−2‖ 0〉. Another simple formula is derived, with which all matrix elements 〈v′‖yn ‖v〉 can be calculated recursively, starting from values of 〈0‖yn‖ 0〉.Keywords
This publication has 12 references indexed in Scilit:
- Morse-oscillator matrix elements appropriate for vibration-rotation intensities of diatomic moleculesThe Journal of Chemical Physics, 1982
- Diatomic molecules as perturbed Morse oscillators. VI. High-precision eigenfunctions.The Journal of Chemical Physics, 1981
- High-accuracy analytic potential function for diatomic molecules; Application to COJournal of Molecular Spectroscopy, 1978
- Diatomic molecules as perturbed Morse oscillators. IV. Franck–Condon factors for very high JThe Journal of Chemical Physics, 1978
- Analytic Rydberg-Klein-Rees potential including effects of higher-order WKB approximationsJournal of Molecular Spectroscopy, 1977
- Diatomic molecules as perturbed Morse oscillators. III. Perturbed eigenfunctions and Franck–Condon factorsThe Journal of Chemical Physics, 1977
- Diatomic molecules as perturbed Morse oscillators. II. Extension to higher-order parametersThe Journal of Chemical Physics, 1976
- Diatomic molecules as perturbed Morse oscillators. I. Energy levelsThe Journal of Chemical Physics, 1976
- Factorization−method treatment of the perturbed Morse oscillatorJournal of Mathematical Physics, 1975
- The Factorization MethodReviews of Modern Physics, 1951