Defects in doped polyacetylene: An a b i n i t i o infrared and Raman spectroscopy of solitons
- 15 February 1988
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 88 (4) , 2859-2860
- https://doi.org/10.1063/1.453976
Abstract
We report complete vibrational spectra, including IR and Raman intensities of C22H24, C21H+23, and C12H++14, as models for pure and doped polyacetylene. The results provide definitive evidence for charged solitonic rather than bipolaronic defects.Keywords
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