Synthesis of hydroxydihydroeremophilone
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 3,p. 282-285
- https://doi.org/10.1039/p19780000282
Abstract
Hydroxydihydroeremophilone (HDE) has been synthesized from eremophilone by two procedures. In one the kinetic enolate of 1,10-dihydroeremophilone was oxidised with molybdenum peroxide to the 8β-epimeride of HDE, which was then epimerised by acid to HDE. Alternatively the trimethylsilyl ether of the kinetic enolate could be oxidised by peracid to an α-trimethylsilyloxyketone, which was then hydrolysed by acid to HDE.This publication has 1 reference indexed in Scilit:
- Stereochemistry of dialkylcuprate additions to cyclopropyl acrylic esters. An application to the synthesis of (.+-.)-eremophiloneThe Journal of Organic Chemistry, 1977