Soil chemical properties after long‐term n fertilization of bromegrass: Nitrogen rate

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Abstract
Nitrogen (N) fertilizers increase yield and quality of grass forage, and may also alter soil chemical properties. A field experiment was conducted in south‐central Alberta to determine the effect of long‐term application of ammonium nitrate to bromegrass on concentration and downward mobility of soluble NO3‐N, extractable NH4‐N, P, Ca, Mg, and K, and total C and N in a Thin Black Chernozemic loam soil. The fertilizer was applied annually in early spring for 16 years at 0 to 336 kg N/ha. There was little accumulation of NO3‐N in the soil at N rates of 112 kg/ha or less. However, at rates higher than 112 kg N/ha there was accumulation of NO3‐N in the 15–30 and 30–60 cm layers, but very little in the 90–120 cm depth. The NH4‐N accumulated in the 0–5 cm layer when the fertilizer was applied at rates between 168 to 280 kg N/ha and in the 5–10 cm layer at N rates exceeding 280 kg/ha. There was a decline in extractable P in soil with N application up to 84 kg N/ha rate, while it increased with high N rates. The increasing amounts of applied N resulted in a decline in extractable soil Ca, Mg and K, and this decrease was more pronounced in the 0–5,5–10,10–15, and 15–30 cm layers for K, 0–5 and 5–10 cm layers for Ca, and 0–5, 5–10, and 10–15 cm layers for Mg. There was a build‐up of total C and N in the surface soil with increasing rate of applied N.